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LIFE.com: Country Music's Best Couples

Time Well Spent

Country's Brad Paisley wed Hollywood actress Kimberly Williams in 2003, two years after he'd become smitten while watching her in Father of the Bride II and casting her in one of his videos. She's now known as Kimberly Williams-Paisley. (Dimitrios Kambouris/WireImage/LIFE.com)
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