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Billboard's Biggest Duets

'My Boo' by Usher and Alicia Keys, 2004

“Not to be confused with the 1996 hit of the same name by Ghost Town DJs, this ode to having a boyfriend or girlfriend ‘that will always have your heart’ was tailor made for success because of the team of R&B superstars behind it. Not only does the track find Keys' golden tones mingling with Ushers, the was the track co-written by Keys, Usher and Jermaine Dupri with Manuel Seal and Adonis Shropshire. Little wonder, then, that it rocketed to No. 1 and stayed there for six weeks.” (Billboard) (Photo: Frank Micelotta/Getty Images)

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