Brad Pitt and Gwyneth Paltrow
Before Jennifer Aniston and Angelina Jolie, Brad Pitt had his eyes set on another woman: Gwyneth Paltrow. The two stars started dating in 1994 and were engaged in 1996, but never made it down the aisle. Paltrow later revealed that she called off the wedding because she was not ready for marriage. —XFINITY Entertainment Staff (AP Photo/Kevork Djansezian)
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